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Slide 1 - Reactions of Alcohols Reaction Summary: 4. Hydration: Alkene + water --> alcohol 7. Dehydration: Alcohol + heat --> alkene + H2 8. Oxidation: Pri. Alcohol + (O) --> aldehyde 9. Oxidation: Sec. Alcohol + (O) --> ketone 9B. Oxidation: Tert. Alcohol + (O) --> no reaction 10.Oxidation: Aldehyde + (O) --> Acid 11. Ether Synthesis: Alcohol + alcohol --> ether + HOH
Slide 2 - 4. Hydration Reaction Alkene + HOH --> alcohol HOH molecule adds to carbons with double bond.
Slide 3 - 7. Dehydration of Alcohol to Alkene Subtraction: Remove -OH from alcohol carbon Remove -H from a neighbor carbon
Slide 4 - Reactions of Alcohols
Slide 5 - 8. Oxidation of Primary Alcohol to Aldehyde Subtraction: Remove -H from alcohol group Remove -H from alcohol carbon
Slide 6 - Reactions of Alcohols
Slide 7 - 9. Oxidation of Secondary Alcohol to Ketone Subtraction: Remove -H from alcohol group Remove -H from alcohol carbon
Slide 8 - Reactions of Alcohols
Slide 9 - Reactions of Alcohols
Slide 10 - Reactions of Alcohols
Slide 11 - Reactions of Alcohols
Slide 12 - Reactions of Alcohols
Slide 13 - 10. Oxidation of Aldehyde to Acid Add oxygen from oxidizing agent Insert O between H of carbon double oxygen
Slide 14 - 11. Ether synthesis from 2 alcohols Subtraction: Remove -H from one alcohol group Remove -OH from other alcohol carbon Join two parts
Slide 15 - Reactions of Alcohols